Did this save for a friend and thought this might be useful to someone else so i am putting it here this save will unlock Gadabout (explore all areas) & Completionist (all side Quests) for the Captain scarlet DLC.
Edit: Added X Marks the Spot
X Marks the Spot: Select Normal Mode & hand the quest in then it will pop ( do this before the other two if you want the achievements to look in order)
Load up True Vault Hunter Mode for these two.
Completiontist: Just hand in the final quest & it will pop.
Gadabout: it would not pop on load with a full map so i have left an area in Magnys Lighthouse unexplored just explore it & it will pop instructions on how to get there below.
Travel to the black spot on the map when you get there start on the railing at the back and jump on the vent and then jump on the roof and look for a broken barrier just above you just jump up there (might need a running jump) and enter the room and it should pop.
Video in case text isn't very clear (Not my video)
Save Info incase any wants to use it for anything else
Level 50 Mechromancer with a few orange weapons,orange class mod (not Terra) & a few purple ones all lvl 50.
All missions story & side done in tvhm only dlc not done in p1 everything else is done also has 40 extra skill points modded into it.