Winning and Hoarder are the two hardest-to-obtain achievements of the game which require respectively to complete every stage with a "Perfection!" score and to purchase all the items in the shop.
This save have all the stages cleared with a "Perfection!" score. To unlock "Winning" simply play any stage and complete it with a "Perfection!" score (level 1-1 or 1-2 for example).
For the achievement "Hoarder", there are 500 Gems available and only a Vinyl (Blister, the first one) to purchase for 500 Gems; simply load a stage with a shop (1-2 or 3-1 for example) and purchase the last item to unlock the achievement.
The other achievements will not pop-up randomly, but in theory you could unlock them in the wrong order if you played, say, stage 7-3 (and unlock an achievement for completing it) and then 5-2 (and unlock an achievement for completing it). So yea avoid playing the last stages first if you haven't unlocked the story-related achievements of the previous stages yet.
Scarygirl - Winning and Hoarder.rar (Mirror Mediafire)